Development of a predictive model for polymer/solvent diffusion coefficient calculations

A new calculation procedure for free‐volume parameters is considered in this work by using viscosity prediction methods and the Levenberg‐Marquardt calculation scheme. All parameters used in the Vrentas–Duda free‐volume theory can be estimated from pure component properties. The prediction results are compared with experimental data for some polymer/solvent systems. The diffusion coefficient calculated by Vrentas–Duda theory can be used in the modeling of membrane separation processes. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

整体毡纤维体积分数对CVD增密的影响

将3组不同纤维体积分数的整体毡采用等温CVD进行沉积热解炭增密,结合CVD沉积过程中整体毡内气体传质数学模型,研究了整体毡的纤维体积分数对CVD增密过程的影响,研究结果表明:纤维体积低的整体毡沉积时增重率高;纤维体积分数高的整体毡容易获得较高密度的C/C复合材料;纤维体积分数超过35％的整体毡经过300 h的化学气相沉积,坯体的体积密度能达到1.52 g/cm~3。     

浅谈城市道路立交的概念性方案设计

通过南昌市某快速路的设计实例，认识到搞好快速路沿线各交叉口的方案设计是快速路规划设计的关键内容。道路交叉口设计应注重交通功能分析，满足路口交通需求，同时也不能忽视立交的景观要求。     

矿用交换机用户线接口电路

介绍了一种由新型集成芯片组成的电话用户线接口电路，由用户线功能块DTLM630和可编程单片全双工增量调制解调器CMX639等组成。由于芯片的高度集成化，从而使电路结构简单，使用可靠，是一种新型实用的用户线接口电路。     

Evaluation of Serum Volume Losses During Long-Term Storage

Aliquots of serum collected in a large case-control study of cervical cancer were stored at −70°C for up to 4 years during implementation of the study. When 500 μL serum aliquots were thawed in preparation for carotenoid and vitamin A assays, volumes were noticeably variable and fell below 500 μL in the majority of the samples. We were concerned about evaporation/sublimation during storage of the samples because loss of water would concentrate the analytes of interest. We evaluated the use of density and sodium ion concentration measurements to confirm its occurrence. We found that serum density was an unreliable indicator of extent of volume loss since the anticipated increases in density due to evaporation were of the same magnitude as inter-individual variation in serum density. In contrast, Na⁺ concentration is tightly regulated and would rise if water had been lost from the samples. In a representative sample of serum aliquots from the case-control study, 24 of 25 vials contained less than 500 μL of serum. The mean sodium ion concentration (138.1 ± 3.6 mmol/L) was within the normal range for human serum of 136–145 mmol/L, and no correlation was observed between serum volume and Na⁺ concentration. These results strongly suggest that the observed low volumes were not due to evaporative losses. Instead, the variably low volumes of serum aliquots were probably due to pipetting errors in the initial aliquotting resulting from the use of air-displacement pipettes.     

Optimisation of metallic pigments in coatings by an electrochemical technique and an investigation of manganese powder as pigment for metal rich primers

Zinc dust and manganese powder as pigments were incorporated in epoxy-polyamide and butyl titanate medium, with different pigment volume concentration (PVC) ranging from 20 to 74. These protective coatings were coated on sand blasted mild steel substrates and immersed in 3 wt.% sodium chloride solution and the corrosion current was measured by the Tafel extrapolation method. From the corrosion current produced by these primers, the optimum level of the pigments in these binders was identified. Thus the protective performance of optimised primers was evaluated on a sand blasted mild steel surface by the Tafel polarisation method in 3 wt.% sodium chloride solution, over different periods of time. The results were found to be comparable with the salt spray test and galvanic current measurements. The manganese powder used for this investigation showed that it could be used as an alternative to zinc powder for metal rich primers.     

隆德县大水沟饮水工程建设与管理措施分析

隆德县在大水沟农村饮水工程建设管理中，科学规划，优化设计方案，完善政策措施，创新管理体制和运行机制，尤其是用水户全过程参与工程建设管理、实行“两部制”水价、实施工程定期检查养护制度、建立工程管理单位目标责任考核制度、执行水费统一管理和提留统筹费等一系列做法．确保了国家投资效益的充分发挥和工程的可持续利用．     

Viscous behaviour of glass-forming liquids: a thermodynamic approach

The temperature dependence of the viscosity of the undercooled melts exhibits an important role in the study of nucleation, crystal growth and the glass-forming ability of materials. Several attempts have been made to study the viscous behaviour of the glass-forming melts and these investigations are mainly based on free volume theory as well as on the configurational entropy model. In the present investigation, an attempt has been made to correlate the thermodynamic parameters with the viscosity of the glass-forming melts and to study the temperature dependence of the viscosity of undercooled liquids on the basis of the free volume theory as well as on the basis of the configurational entropy model of Adam and Gibbs. The entire study is confined on the expression for thermodynamic parameters reported by the authors recently. The expression obtained has been successfully applied to study the temperature dependence of the viscosity of the metallic, molecular and oxide glass-forming liquids.     

喇8-182井区聚合物驱不可及孔隙体积研究

喇嘛甸油田喇8-182井区高Ⅱ1-18油层渗透率低、物性差,属于三类油层,是聚合物驱的主力接替潜力层。文中在油层性质对比分析的基础上,应用计算法和数值模拟方法研究了高Ⅱ1-18油层的聚合物驱不可及孔隙体积并进行了对比。研究结果表明,计算法简单易行,成本低,能够充分考虑分子量、矿化度等的影响;但这种方法只考虑了由于孔隙直径过小而导致的不可及孔隙体积,无法表达由于压力梯度不足而造成的不可及孔隙体积,因此计算结果偏小,只适合于分子量的初步优选。数值模拟方法充分考虑了启动压力梯度和压力场的影响,计算结果更加符合实际情况,适合于在已经初步选定分子量范围的情况下,模拟不可及孔隙体积。不可及孔隙体积随注入速度增加而减小,高Ⅱ1-18油层不可及孔隙体积在0.2～0.3之间。最后建议喇8-182井区聚合物驱注入速度控制在0.2PV/a以内。